DC magnetron sputter deposited vanadia catalysts for oxidation processes

Maria Olea; Isabelle Sack; Veerle Balcaen; Guy B Marin; Hilde Poelman; Karin Eufinger; Dirk Poelman; Roger de Gryse; J. S. Paul; Bert F E  Sels

doi:10.1016/j.apcata.2006.10.035

DC magnetron sputter deposited vanadia catalysts for oxidation processes

Maria Olea, Isabelle Sack, Veerle Balcaen, Guy B Marin, Hilde Poelman, Karin Eufinger, Dirk Poelman, Roger de Gryse, J. S. Paul, Bert F E Sels

SCEDT Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

New model catalysts were prepared by applying DC magnetron sputter deposition of vanadia onto ZrO2/SiO2 and TiO2/ZrO2/SiO2 supports and were characterized by X-ray diffraction (XRD), X-ray energy dispersive spectrometry (EDX), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma emission spectroscopy (ICP) and catalytic activity towards propane and isobutane oxidative dehydrogenation. Titania interlayer enhances oxidative dehydrogenation activity and decreases the total oxidation side reactions. A Mars–van Krevelen mechanism is operative.

Original language	English
Pages (from-to)	37-44
Journal	Applied Catalysis A: General
Volume	318
DOIs	https://doi.org/10.1016/j.apcata.2006.10.035
Publication status	Published - 20 Feb 2007

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title = "DC magnetron sputter deposited vanadia catalysts for oxidation processes",

abstract = "New model catalysts were prepared by applying DC magnetron sputter deposition of vanadia onto ZrO2/SiO2 and TiO2/ZrO2/SiO2 supports and were characterized by X-ray diffraction (XRD), X-ray energy dispersive spectrometry (EDX), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma emission spectroscopy (ICP) and catalytic activity towards propane and isobutane oxidative dehydrogenation. Titania interlayer enhances oxidative dehydrogenation activity and decreases the total oxidation side reactions. A Mars–van Krevelen mechanism is operative.",

author = "Maria Olea and Isabelle Sack and Veerle Balcaen and Marin, {Guy B} and Hilde Poelman and Karin Eufinger and Dirk Poelman and {de Gryse}, Roger and Paul, {J. S.} and Sels, {Bert F E}",

year = "2007",

month = feb,

day = "20",

doi = "10.1016/j.apcata.2006.10.035",

language = "English",

volume = "318",

pages = "37--44",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - DC magnetron sputter deposited vanadia catalysts for oxidation processes

AU - Olea, Maria

AU - Sack, Isabelle

AU - Balcaen, Veerle

AU - Marin, Guy B

AU - Poelman, Hilde

AU - Eufinger, Karin

AU - Poelman, Dirk

AU - de Gryse, Roger

AU - Paul, J. S.

AU - Sels, Bert F E

PY - 2007/2/20

Y1 - 2007/2/20

N2 - New model catalysts were prepared by applying DC magnetron sputter deposition of vanadia onto ZrO2/SiO2 and TiO2/ZrO2/SiO2 supports and were characterized by X-ray diffraction (XRD), X-ray energy dispersive spectrometry (EDX), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma emission spectroscopy (ICP) and catalytic activity towards propane and isobutane oxidative dehydrogenation. Titania interlayer enhances oxidative dehydrogenation activity and decreases the total oxidation side reactions. A Mars–van Krevelen mechanism is operative.

AB - New model catalysts were prepared by applying DC magnetron sputter deposition of vanadia onto ZrO2/SiO2 and TiO2/ZrO2/SiO2 supports and were characterized by X-ray diffraction (XRD), X-ray energy dispersive spectrometry (EDX), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma emission spectroscopy (ICP) and catalytic activity towards propane and isobutane oxidative dehydrogenation. Titania interlayer enhances oxidative dehydrogenation activity and decreases the total oxidation side reactions. A Mars–van Krevelen mechanism is operative.

UR - http://linkinghub.elsevier.com/retrieve/pii/S0926860X06007721

U2 - 10.1016/j.apcata.2006.10.035

DO - 10.1016/j.apcata.2006.10.035

M3 - Article

SN - 0926-860X

VL - 318

SP - 37

EP - 44

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

ER -

DC magnetron sputter deposited vanadia catalysts for oxidation processes

Abstract

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