Diastereoselectivity and molecular recognition of mercury(II) ions

Anna Reynal; Josep Albero; Anton Vidal-Ferran; Emilio Palomares

doi:10.1016/j.inoche.2008.11.029

Diastereoselectivity and molecular recognition of mercury(II) ions

Anna Reynal, Josep Albero, Anton Vidal-Ferran, Emilio Palomares

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Two diastereoisomers of a new heteroleptic ruthenium cis-dithiocyanate dicarboxy-bipyridyl phenanthrolyl complex have been synthesized and characterized. This type of complexes can selectively bind mercury ions through the sulphur atoms on the thiocyanate groups. The properties of these complexes as chemosensor towards Hg²⁺ in solution and anchored onto a mesoporous Al₂O₃ film have been studied and analysed. A different level of sensitivity versus mercury ions in aqueous solutions was observed for each stereoisomer.

Original language	English
Pages (from-to)	131-134
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2008.11.029
Publication status	Published - 1 Feb 2009

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10.1016/j.inoche.2008.11.029

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abstract = "Two diastereoisomers of a new heteroleptic ruthenium cis-dithiocyanate dicarboxy-bipyridyl phenanthrolyl complex have been synthesized and characterized. This type of complexes can selectively bind mercury ions through the sulphur atoms on the thiocyanate groups. The properties of these complexes as chemosensor towards Hg2+ in solution and anchored onto a mesoporous Al2O3 film have been studied and analysed. A different level of sensitivity versus mercury ions in aqueous solutions was observed for each stereoisomer.",

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AU - Albero, Josep

AU - Vidal-Ferran, Anton

AU - Palomares, Emilio

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AB - Two diastereoisomers of a new heteroleptic ruthenium cis-dithiocyanate dicarboxy-bipyridyl phenanthrolyl complex have been synthesized and characterized. This type of complexes can selectively bind mercury ions through the sulphur atoms on the thiocyanate groups. The properties of these complexes as chemosensor towards Hg2+ in solution and anchored onto a mesoporous Al2O3 film have been studied and analysed. A different level of sensitivity versus mercury ions in aqueous solutions was observed for each stereoisomer.

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JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 2

ER -

Diastereoselectivity and molecular recognition of mercury(II) ions

Abstract

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