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Difference frequency generation in periodically poled lithium niobate and its use in the detection of atmospheric methane

  • H. Y. Clark
  • , L. Corner
  • , W. Denzer
  • , G. Hancock
  • , Andrew Hutchinson
  • , Meez Islam
  • , R. Peverall
  • , G. A.D. Ritchie

Research output: Contribution to journalArticlepeer-review

Abstract

Continuous wave mid-infrared radiation at 3.36 μm (power ≈ 18 μW) has been produced by difference frequency generation of the fundamental of a YAG laser at 1064 nm (220 mW) with a fibre pigtailed DFB diode laser operating at 1560 nm (50 mW) in periodically poled lithium niobate. The idler radiation has been used to make real-time measurements of ambient methane present in our laboratory using wavelength modulation spectroscopy via the P(4) multiplet transitions within the ν 3 band. We demonstrate a minimum detectable concentration of 47 ppb over a path length of 0.71 m in a 1 s observation time. Measurements of the pressure broadening and shift parameters for these lines are presented for methane in the presence of air, nitrogen and argon.

Original languageEnglish
Pages (from-to)102-108
Number of pages7
JournalChemical Physics Letters
Volume399
Issue number1-3
DOIs
Publication statusPublished - 21 Nov 2004

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