Encapsulation of hydrogen in cadmium-exchanged zeolite rho: temperature-programmed diffusion studies

Venkatesan Venkata Krishnan; Steven L. Suib; David R.  Corbin; Stephan Schwarz; Glover E. Jones

doi:10.1039/CC9960000395

Encapsulation of hydrogen in cadmium-exchanged zeolite rho: temperature-programmed diffusion studies

Venkatesan Venkata Krishnan
, Steven L. Suib
, David R. Corbin
, Stephan Schwarz
, Glover E. Jones

Research output: Contribution to journal › Article › peer-review

Abstract

Cadmium-exchanged zeolite rho encapsulates 161 micromol g-1 of hydrogen at 100 "C and 620 micro mol g-1 at 200 deg C, (in 2 h and at 1 atm), the highest ever observed for any zeolite at 1 atm; hydrogen-exchanged zeolite rho, however, shows negligible uptake of hydrogen, providing evidence that the cadmium ion is directly responsible for hydrogen encapsulation.

Original language	English
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/CC9960000395
Publication status	Published - 7 Feb 1996
Externally published	Yes

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title = "Encapsulation of hydrogen in cadmium-exchanged zeolite rho: temperature-programmed diffusion studies",

abstract = "Cadmium-exchanged zeolite rho encapsulates 161 micromol g-1 of hydrogen at 100 {"}C and 620 micro mol g-1 at 200 deg C, (in 2 h and at 1 atm), the highest ever observed for any zeolite at 1 atm; hydrogen-exchanged zeolite rho, however, shows negligible uptake of hydrogen, providing evidence that the cadmium ion is directly responsible for hydrogen encapsulation.",

author = "Krishnan, \{Venkatesan Venkata\} and Suib, \{Steven L.\} and Corbin, \{David R.\} and Stephan Schwarz and Jones, \{Glover E.\}",

year = "1996",

month = feb,

day = "7",

doi = "10.1039/CC9960000395",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Encapsulation of hydrogen in cadmium-exchanged zeolite rho

T2 - temperature-programmed diffusion studies

AU - Krishnan, Venkatesan Venkata

AU - Suib, Steven L.

AU - Corbin, David R.

AU - Schwarz, Stephan

AU - Jones, Glover E.

PY - 1996/2/7

Y1 - 1996/2/7

N2 - Cadmium-exchanged zeolite rho encapsulates 161 micromol g-1 of hydrogen at 100 "C and 620 micro mol g-1 at 200 deg C, (in 2 h and at 1 atm), the highest ever observed for any zeolite at 1 atm; hydrogen-exchanged zeolite rho, however, shows negligible uptake of hydrogen, providing evidence that the cadmium ion is directly responsible for hydrogen encapsulation.

AB - Cadmium-exchanged zeolite rho encapsulates 161 micromol g-1 of hydrogen at 100 "C and 620 micro mol g-1 at 200 deg C, (in 2 h and at 1 atm), the highest ever observed for any zeolite at 1 atm; hydrogen-exchanged zeolite rho, however, shows negligible uptake of hydrogen, providing evidence that the cadmium ion is directly responsible for hydrogen encapsulation.

U2 - 10.1039/CC9960000395

DO - 10.1039/CC9960000395

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

Encapsulation of hydrogen in cadmium-exchanged zeolite rho: temperature-programmed diffusion studies

Abstract

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