Generation of average mass values and end group information of polymers by means of a combination of matrix-assisted laser desorption/ionization- mass spectrometry and liquid secondary ion-tandem mass spectrometry

Anthony T. Jackson; Keith R. Jennings; James  Scrivens

doi:10.1016/S1044-0305(96)00131-6

Generation of average mass values and end group information of polymers by means of a combination of matrix-assisted laser desorption/ionization- mass spectrometry and liquid secondary ion-tandem mass spectrometry

Anthony T. Jackson
, Keith R. Jennings
, James Scrivens

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

Matrix-assisted laser desorption/ionization-mass spectrometry (MALDI- MS) and liquid secondary ion tandem mass spectrometry (LSI-MS/MS) have been applied to the analysis of synthetic polymers to generate values for the average mass and the mass of the end groups. The average mass values were calculated for polymethylmethacrylate and polystyrene standards from the MALDI-MS data. Abundant fragment ions of the polymers, generated by means of LSI-MS/MS, were consistent with the known structures of the end groups of the polymers. Furthermore, losses from the side chains of the polymers were also observed in the LSI-MS/MS spectra.

Original language	English
Pages (from-to)	76-85
Number of pages	10
Journal	Journal of the American Society for Mass Spectrometry
Volume	8
Issue number	1
DOIs	https://doi.org/10.1016/S1044-0305(96)00131-6
Publication status	Published - 1 Jan 1997

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Jackson, A. T., Jennings, K. R., & Scrivens, J. (1997). Generation of average mass values and end group information of polymers by means of a combination of matrix-assisted laser desorption/ionization- mass spectrometry and liquid secondary ion-tandem mass spectrometry. Journal of the American Society for Mass Spectrometry, 8(1), 76-85. https://doi.org/10.1016/S1044-0305(96)00131-6

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title = "Generation of average mass values and end group information of polymers by means of a combination of matrix-assisted laser desorption/ionization- mass spectrometry and liquid secondary ion-tandem mass spectrometry",

abstract = "Matrix-assisted laser desorption/ionization-mass spectrometry (MALDI- MS) and liquid secondary ion tandem mass spectrometry (LSI-MS/MS) have been applied to the analysis of synthetic polymers to generate values for the average mass and the mass of the end groups. The average mass values were calculated for polymethylmethacrylate and polystyrene standards from the MALDI-MS data. Abundant fragment ions of the polymers, generated by means of LSI-MS/MS, were consistent with the known structures of the end groups of the polymers. Furthermore, losses from the side chains of the polymers were also observed in the LSI-MS/MS spectra.",

author = "Jackson, \{Anthony T.\} and Jennings, \{Keith R.\} and James Scrivens",

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doi = "10.1016/S1044-0305(96)00131-6",

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Jackson, AT, Jennings, KR & Scrivens, J 1997, 'Generation of average mass values and end group information of polymers by means of a combination of matrix-assisted laser desorption/ionization- mass spectrometry and liquid secondary ion-tandem mass spectrometry', Journal of the American Society for Mass Spectrometry, vol. 8, no. 1, pp. 76-85. https://doi.org/10.1016/S1044-0305(96)00131-6

Generation of average mass values and end group information of polymers by means of a combination of matrix-assisted laser desorption/ionization- mass spectrometry and liquid secondary ion-tandem mass spectrometry. / Jackson, Anthony T.; Jennings, Keith R.; Scrivens, James .
In: Journal of the American Society for Mass Spectrometry, Vol. 8, No. 1, 01.01.1997, p. 76-85.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Generation of average mass values and end group information of polymers by means of a combination of matrix-assisted laser desorption/ionization- mass spectrometry and liquid secondary ion-tandem mass spectrometry

AU - Jackson, Anthony T.

AU - Jennings, Keith R.

AU - Scrivens, James

PY - 1997/1/1

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N2 - Matrix-assisted laser desorption/ionization-mass spectrometry (MALDI- MS) and liquid secondary ion tandem mass spectrometry (LSI-MS/MS) have been applied to the analysis of synthetic polymers to generate values for the average mass and the mass of the end groups. The average mass values were calculated for polymethylmethacrylate and polystyrene standards from the MALDI-MS data. Abundant fragment ions of the polymers, generated by means of LSI-MS/MS, were consistent with the known structures of the end groups of the polymers. Furthermore, losses from the side chains of the polymers were also observed in the LSI-MS/MS spectra.

AB - Matrix-assisted laser desorption/ionization-mass spectrometry (MALDI- MS) and liquid secondary ion tandem mass spectrometry (LSI-MS/MS) have been applied to the analysis of synthetic polymers to generate values for the average mass and the mass of the end groups. The average mass values were calculated for polymethylmethacrylate and polystyrene standards from the MALDI-MS data. Abundant fragment ions of the polymers, generated by means of LSI-MS/MS, were consistent with the known structures of the end groups of the polymers. Furthermore, losses from the side chains of the polymers were also observed in the LSI-MS/MS spectra.

UR - https://www.scopus.com/pages/publications/0031036157

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DO - 10.1016/S1044-0305(96)00131-6

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SN - 1044-0305

VL - 8

SP - 76

EP - 85

JO - Journal of the American Society for Mass Spectrometry

JF - Journal of the American Society for Mass Spectrometry

IS - 1

ER -

Generation of average mass values and end group information of polymers by means of a combination of matrix-assisted laser desorption/ionization- mass spectrometry and liquid secondary ion-tandem mass spectrometry

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