High resolution visualization of the redox activity of Li2O2 in non-aqueous media:: conformal layer vs. toroid structure

Pei San (Sharel) E; Mingkyung Kang; Paul Wilson; Lingcong Meng; David Perry; Andrew Basile; Patrick R.  Unwin

doi:https://doi.org/10.1039/C7CC09957F

High resolution visualization of the redox activity of Li2O2 in non-aqueous media: conformal layer vs. toroid structure

Pei San (Sharel) E, Mingkyung Kang, Paul Wilson, Lingcong Meng, David Perry, Andrew Basile, Patrick R. Unwin

Research output: Contribution to journal › Article › peer-review

Abstract

A strong relationship between the surface structure and the redox activity of Li2O2 is visualized directly using scanning electrochemical cell microscopy, employing a dual-barrel nanopipette containing a unique gel polymer electrolyte. These measurements reveal considerable local heterogeneity with significantly enhanced electrochemical activity at toroidal Li2O2 structures when compared to the conformal layer that is usually formed on the cathode of Li–O2 batteries.

Original language	English
Pages (from-to)	3053–3056
Number of pages	4
Journal	Chemical Communications
Volume	54
DOIs	https://doi.org/10.1039/C7CC09957F
Publication status	Published - 19 Feb 2018

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title = "High resolution visualization of the redox activity of Li2O2 in non-aqueous media:: conformal layer vs. toroid structure",

abstract = "A strong relationship between the surface structure and the redox activity of Li2O2 is visualized directly using scanning electrochemical cell microscopy, employing a dual-barrel nanopipette containing a unique gel polymer electrolyte. These measurements reveal considerable local heterogeneity with significantly enhanced electrochemical activity at toroidal Li2O2 structures when compared to the conformal layer that is usually formed on the cathode of Li–O2 batteries.",

author = "E, {Pei San (Sharel)} and Mingkyung Kang and Paul Wilson and Lingcong Meng and David Perry and Andrew Basile and Unwin, {Patrick R.}",

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T1 - High resolution visualization of the redox activity of Li2O2 in non-aqueous media:

T2 - conformal layer vs. toroid structure

AU - E, Pei San (Sharel)

AU - Kang, Mingkyung

AU - Wilson, Paul

AU - Meng, Lingcong

AU - Perry, David

AU - Basile, Andrew

AU - Unwin, Patrick R.

PY - 2018/2/19

Y1 - 2018/2/19

N2 - A strong relationship between the surface structure and the redox activity of Li2O2 is visualized directly using scanning electrochemical cell microscopy, employing a dual-barrel nanopipette containing a unique gel polymer electrolyte. These measurements reveal considerable local heterogeneity with significantly enhanced electrochemical activity at toroidal Li2O2 structures when compared to the conformal layer that is usually formed on the cathode of Li–O2 batteries.

AB - A strong relationship between the surface structure and the redox activity of Li2O2 is visualized directly using scanning electrochemical cell microscopy, employing a dual-barrel nanopipette containing a unique gel polymer electrolyte. These measurements reveal considerable local heterogeneity with significantly enhanced electrochemical activity at toroidal Li2O2 structures when compared to the conformal layer that is usually formed on the cathode of Li–O2 batteries.

U2 - https://doi.org/10.1039/C7CC09957F

DO - https://doi.org/10.1039/C7CC09957F

M3 - Article

VL - 54

SP - 3053

EP - 3056

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

ER -

High resolution visualization of the redox activity of Li2O2 in non-aqueous media: conformal layer vs. toroid structure

Abstract

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