Homonuclear spin-spin coupling through iron in simple inorganic ions

Anthony R. Butler; Christopher Glidewell; Andrew R. Hyde; Joseph McGinnis

doi:10.1016/S0277-5387(00)88076-6

Homonuclear spin-spin coupling through iron in simple inorganic ions

Anthony R. Butler, Christopher Glidewell, Andrew R. Hyde, Joseph McGinnis

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9 Citations (Scopus)

Abstract

Homonuclear spin-spin coupling, ₂J(₁₃CFe₁₃C), has been observed in the nitroprusside ion, [Fe(CN)₅NO]^2-, and the coupling ₂J(¹⁵NFe¹⁵N) has been observed in the Roussin anions [Fe₄S₃(NO)₇]^- and [Fe₄Se₃(NO)₇]^-: the ¹⁵N NMR spectrum of [Fe₄Se₃(¹⁵NO)₇]^- provides a definitive proof of the structure for this anion.

Original language	English
Pages (from-to)	1165-1167
Number of pages	3
Journal	Polyhedron
Volume	3
Issue number	9-10
DOIs	https://doi.org/10.1016/S0277-5387(00)88076-6
Publication status	Published - 1 Jan 1984

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title = "Homonuclear spin-spin coupling through iron in simple inorganic ions",

abstract = "Homonuclear spin-spin coupling, 2J(13CFe13C), has been observed in the nitroprusside ion, [Fe(CN)5NO]2-, and the coupling 2J(15NFe15N) has been observed in the Roussin anions [Fe4S3(NO)7]- and [Fe4Se3(NO)7]-: the 15N NMR spectrum of [Fe4Se3(15NO)7]- provides a definitive proof of the structure for this anion.",

author = "Butler, {Anthony R.} and Christopher Glidewell and Hyde, {Andrew R.} and Joseph McGinnis",

year = "1984",

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doi = "10.1016/S0277-5387(00)88076-6",

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pages = "1165--1167",

journal = "Polyhedron",

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TY - JOUR

T1 - Homonuclear spin-spin coupling through iron in simple inorganic ions

AU - Butler, Anthony R.

AU - Glidewell, Christopher

AU - Hyde, Andrew R.

AU - McGinnis, Joseph

PY - 1984/1/1

Y1 - 1984/1/1

N2 - Homonuclear spin-spin coupling, 2J(13CFe13C), has been observed in the nitroprusside ion, [Fe(CN)5NO]2-, and the coupling 2J(15NFe15N) has been observed in the Roussin anions [Fe4S3(NO)7]- and [Fe4Se3(NO)7]-: the 15N NMR spectrum of [Fe4Se3(15NO)7]- provides a definitive proof of the structure for this anion.

AB - Homonuclear spin-spin coupling, 2J(13CFe13C), has been observed in the nitroprusside ion, [Fe(CN)5NO]2-, and the coupling 2J(15NFe15N) has been observed in the Roussin anions [Fe4S3(NO)7]- and [Fe4Se3(NO)7]-: the 15N NMR spectrum of [Fe4Se3(15NO)7]- provides a definitive proof of the structure for this anion.

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U2 - 10.1016/S0277-5387(00)88076-6

DO - 10.1016/S0277-5387(00)88076-6

M3 - Article

AN - SCOPUS:1842337867

SN - 0277-5387

VL - 3

SP - 1165

EP - 1167

JO - Polyhedron

JF - Polyhedron

IS - 9-10

ER -

Homonuclear spin-spin coupling through iron in simple inorganic ions

Abstract

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