Homonuclear spin-spin coupling through iron in simple inorganic ions

Anthony R. Butler, Christopher Glidewell, Andrew R. Hyde, Joseph McGinnis

Research output: Contribution to journalArticleResearchpeer-review

9 Citations (Scopus)

Abstract

Homonuclear spin-spin coupling, 2J(13CFe13C), has been observed in the nitroprusside ion, [Fe(CN)5NO]2-, and the coupling 2J(15NFe15N) has been observed in the Roussin anions [Fe4S3(NO)7]- and [Fe4Se3(NO)7]-: the 15N NMR spectrum of [Fe4Se3(15NO)7]- provides a definitive proof of the structure for this anion.

Original languageEnglish
Pages (from-to)1165-1167
Number of pages3
JournalPolyhedron
Volume3
Issue number9-10
DOIs
Publication statusPublished - 1 Jan 1984

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spin-spin coupling
Anions
Negative ions
Iron
Ions
anions
iron
Nitroprusside
ions
Nuclear magnetic resonance
nuclear magnetic resonance

Cite this

Butler, Anthony R. ; Glidewell, Christopher ; Hyde, Andrew R. ; McGinnis, Joseph. / Homonuclear spin-spin coupling through iron in simple inorganic ions. In: Polyhedron. 1984 ; Vol. 3, No. 9-10. pp. 1165-1167.
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Homonuclear spin-spin coupling through iron in simple inorganic ions. / Butler, Anthony R.; Glidewell, Christopher; Hyde, Andrew R.; McGinnis, Joseph.

In: Polyhedron, Vol. 3, No. 9-10, 01.01.1984, p. 1165-1167.

Research output: Contribution to journalArticleResearchpeer-review

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AU - Glidewell, Christopher

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N2 - Homonuclear spin-spin coupling, 2J(13CFe13C), has been observed in the nitroprusside ion, [Fe(CN)5NO]2-, and the coupling 2J(15NFe15N) has been observed in the Roussin anions [Fe4S3(NO)7]- and [Fe4Se3(NO)7]-: the 15N NMR spectrum of [Fe4Se3(15NO)7]- provides a definitive proof of the structure for this anion.

AB - Homonuclear spin-spin coupling, 2J(13CFe13C), has been observed in the nitroprusside ion, [Fe(CN)5NO]2-, and the coupling 2J(15NFe15N) has been observed in the Roussin anions [Fe4S3(NO)7]- and [Fe4Se3(NO)7]-: the 15N NMR spectrum of [Fe4Se3(15NO)7]- provides a definitive proof of the structure for this anion.

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