TY - JOUR
T1 - Hydrogen production from the decomposition of hydrogen iodide over nanosized nickel-oxide-zirconia catalysts prepared by solution-combustion techniques
AU - Singhania, Amit
AU - Krishnan, Venkatesan
AU - Bhaskarwar, Ashok N.
AU - Bhargava, Bharat
AU - Parvatalu, Damaraju
AU - Banerjee, Satinath
PY - 2017/4
Y1 - 2017/4
N2 - NiO/ZrO2 prepared by solution-combustion method (SCM) showed near equilibrium conversions of hydrogen iodide to hydrogen and iodine at 500 °C–550 °C without any performance degradation over 50 h. XRD data of the catalyst after 10 h of reaction were compared with the same after a TPR step in H2/Ar on another catalyst sample, to verify Ni-ex-solution. Ni is clearly visible in the XRD after TPR, although it was not observed under reaction conditions (HI/H2O/N2), even after 10 h. Instead, the onset of monoclinic ZrO2 is observed after reaction, which was not visible after TPR.
AB - NiO/ZrO2 prepared by solution-combustion method (SCM) showed near equilibrium conversions of hydrogen iodide to hydrogen and iodine at 500 °C–550 °C without any performance degradation over 50 h. XRD data of the catalyst after 10 h of reaction were compared with the same after a TPR step in H2/Ar on another catalyst sample, to verify Ni-ex-solution. Ni is clearly visible in the XRD after TPR, although it was not observed under reaction conditions (HI/H2O/N2), even after 10 h. Instead, the onset of monoclinic ZrO2 is observed after reaction, which was not visible after TPR.
U2 - 10.1016/j.catcom.2017.01.020
DO - 10.1016/j.catcom.2017.01.020
M3 - Article
SN - 1566-7367
VL - 93
SP - 5
EP - 9
JO - Catalysis Communications
JF - Catalysis Communications
ER -