Impregnation of palm shell activated carbon with polyethyleneimine and its effects on Cd2+ adsorption

Chun-Yang Yin, Mohamed Kheireddine Aroua, Wan Mohd Ashri Wan Daud

    Research output: Contribution to journalArticleResearchpeer-review

    Abstract

    Palm shell activated carbon (AC) was impregnated with low (LMW) and high molecular weight (HMW) polyethyleneimine (PEI) via batch adsorption. The maximum amount of LMW PEI adsorbed on AC was determined to be approximately 425 mg/g carbon while the maximum adsorbed HMW PEI was 2.8 mg/g carbon. The LMW PEI adsorption data fitted the Langmuir isotherm better than the Freundlich isotherm. The PEI impregnated AC were characterized via nitrogen adsorption, scanning electron microscopy, elemental analysis, thermogravimetric, Fourier transform infra red and pH drift analyses. Only LMW PEI could be successfully impregnated as monolayers on the surface of the micropores. This impregnation leads to drastic reduction of surface area and pore volume whereas impregnation of HMW PEI does not significantly affect the physical characteristics of the AC. LMW PEI impregnation appears to enhance Cd2+ adsorption capacity of the AC while HMW PEI impregnation is found to have an opposite effect. This result shows that LMW PEI impregnation technique may have the potential to improve the batch adsorption capacity of AC for other transition metal ion adsorption as well.
    Original languageEnglish
    Pages (from-to)128-136
    JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
    Volume307
    Issue number1-3
    DOIs
    Publication statusPublished - 15 Oct 2007

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    Polyethyleneimine
    activated carbon
    Impregnation
    Activated carbon
    Adsorption
    adsorption
    molecular weight
    Molecular weight
    Isotherms
    isotherms
    Carbon
    carbon
    Fourier analysis
    Transition metals
    Metal ions
    Monolayers
    metal ions
    Fourier transforms
    transition metals
    Nitrogen

    Cite this

    Yin, Chun-Yang ; Aroua, Mohamed Kheireddine ; Daud, Wan Mohd Ashri Wan. / Impregnation of palm shell activated carbon with polyethyleneimine and its effects on Cd2+ adsorption. In: Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2007 ; Vol. 307, No. 1-3. pp. 128-136.
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    abstract = "Palm shell activated carbon (AC) was impregnated with low (LMW) and high molecular weight (HMW) polyethyleneimine (PEI) via batch adsorption. The maximum amount of LMW PEI adsorbed on AC was determined to be approximately 425 mg/g carbon while the maximum adsorbed HMW PEI was 2.8 mg/g carbon. The LMW PEI adsorption data fitted the Langmuir isotherm better than the Freundlich isotherm. The PEI impregnated AC were characterized via nitrogen adsorption, scanning electron microscopy, elemental analysis, thermogravimetric, Fourier transform infra red and pH drift analyses. Only LMW PEI could be successfully impregnated as monolayers on the surface of the micropores. This impregnation leads to drastic reduction of surface area and pore volume whereas impregnation of HMW PEI does not significantly affect the physical characteristics of the AC. LMW PEI impregnation appears to enhance Cd2+ adsorption capacity of the AC while HMW PEI impregnation is found to have an opposite effect. This result shows that LMW PEI impregnation technique may have the potential to improve the batch adsorption capacity of AC for other transition metal ion adsorption as well.",
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    Impregnation of palm shell activated carbon with polyethyleneimine and its effects on Cd2+ adsorption. / Yin, Chun-Yang; Aroua, Mohamed Kheireddine; Daud, Wan Mohd Ashri Wan.

    In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 307, No. 1-3, 15.10.2007, p. 128-136.

    Research output: Contribution to journalArticleResearchpeer-review

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