Influence of pH on the characteristics of zinc tris (thiourea) sulfate (ZTS) single crystals

P.M. Ushasree, R. Jayavel, P. Ramasamy

Research output: Contribution to journalArticlepeer-review

Abstract

Growth of bulk ZTS single crystals from aqueous solution by low temperature solution growth technique has been reported. The influence of pH on the structural and mechanical properties has been discussed. The FTIR spectra taken for the crystals grown at different pH values reveal that while decreasing the pH more number of sulfate ions is introduced in the coordination sphere of ZTS leading to the increase in the growth rate along [100] direction. The dielectric constant for ZTS single crystals has been determined. Vicker’s microhardness studies show that the crystals grown at lower pH are harder than that grown at higher pH values.
Original languageEnglish
Pages (from-to)270-274
Number of pages5
JournalMaterials Chemistry and Physics
Volume61
Issue number3
Early online date19 Oct 1999
DOIs
Publication statusPublished - 1 Nov 1999
Externally publishedYes

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