Jet-nebulizer-spray coated copper zinc tin sulphide film for low cost platinum-free electrocatalyst in solar cells

D David Kirubakaran; Sudhagar Pitchaimuthu; C Ravi Dhas; Prabhakaran Selvaraj; S Zh Karazhanov; Senthilarasu Sundaram

doi:10.1016/j.matlet.2018.02.122

Jet-nebulizer-spray coated copper zinc tin sulphide film for low cost platinum-free electrocatalyst in solar cells

D David Kirubakaran
, Sudhagar Pitchaimuthu
, C Ravi Dhas
, Prabhakaran Selvaraj
, S Zh Karazhanov
, Senthilarasu Sundaram

Research output: Contribution to journal › Article › peer-review

Abstract

The copper zinc tin sulphide (CZTS) alloy is a promising p-type earth abundant alloy that received profound attention as an electron driven dark catalyst in electrocatalytic reduction reaction. We report about fabrication of p-type CZTS film with the jet nebulizer assisted spray (JNS) coating technique. The electrocatalytic activity of the as-synthesized CZTS electrode is studied at tri-iodide reduction reactions and is tested as Pt-free electrocatalyst in proof-of-concept type device. Under identical experimental conditions the CZTS counter electrode- and platinum electrode-based dye-sensitised solar cells result similar photocurrent density of ∼10 mA cm−2. These results encourage applications of the aero-sol controlled spray coated CZTS films as the Pt-free electrocatalyst, where reduction reaction takes a key role in energy conversion and biosensing.

Original language	English
Pages (from-to)	122-125
Number of pages	4
Journal	Materials Letters
Volume	220
DOIs	https://doi.org/10.1016/j.matlet.2018.02.122
Publication status	Published - 1 Mar 2018
Externally published	Yes

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title = "Jet-nebulizer-spray coated copper zinc tin sulphide film for low cost platinum-free electrocatalyst in solar cells",

abstract = "The copper zinc tin sulphide (CZTS) alloy is a promising p-type earth abundant alloy that received profound attention as an electron driven dark catalyst in electrocatalytic reduction reaction. We report about fabrication of p-type CZTS film with the jet nebulizer assisted spray (JNS) coating technique. The electrocatalytic activity of the as-synthesized CZTS electrode is studied at tri-iodide reduction reactions and is tested as Pt-free electrocatalyst in proof-of-concept type device. Under identical experimental conditions the CZTS counter electrode- and platinum electrode-based dye-sensitised solar cells result similar photocurrent density of ∼10 mA cm−2. These results encourage applications of the aero-sol controlled spray coated CZTS films as the Pt-free electrocatalyst, where reduction reaction takes a key role in energy conversion and biosensing.",

author = "Kirubakaran, \{D David\} and Sudhagar Pitchaimuthu and Dhas, \{C Ravi\} and Prabhakaran Selvaraj and Karazhanov, \{S Zh\} and Senthilarasu Sundaram",

year = "2018",

month = mar,

day = "1",

doi = "10.1016/j.matlet.2018.02.122",

language = "English",

volume = "220",

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journal = "Materials Letters",

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T1 - Jet-nebulizer-spray coated copper zinc tin sulphide film for low cost platinum-free electrocatalyst in solar cells

AU - Kirubakaran, D David

AU - Pitchaimuthu, Sudhagar

AU - Dhas, C Ravi

AU - Selvaraj, Prabhakaran

AU - Karazhanov, S Zh

AU - Sundaram, Senthilarasu

PY - 2018/3/1

Y1 - 2018/3/1

N2 - The copper zinc tin sulphide (CZTS) alloy is a promising p-type earth abundant alloy that received profound attention as an electron driven dark catalyst in electrocatalytic reduction reaction. We report about fabrication of p-type CZTS film with the jet nebulizer assisted spray (JNS) coating technique. The electrocatalytic activity of the as-synthesized CZTS electrode is studied at tri-iodide reduction reactions and is tested as Pt-free electrocatalyst in proof-of-concept type device. Under identical experimental conditions the CZTS counter electrode- and platinum electrode-based dye-sensitised solar cells result similar photocurrent density of ∼10 mA cm−2. These results encourage applications of the aero-sol controlled spray coated CZTS films as the Pt-free electrocatalyst, where reduction reaction takes a key role in energy conversion and biosensing.

AB - The copper zinc tin sulphide (CZTS) alloy is a promising p-type earth abundant alloy that received profound attention as an electron driven dark catalyst in electrocatalytic reduction reaction. We report about fabrication of p-type CZTS film with the jet nebulizer assisted spray (JNS) coating technique. The electrocatalytic activity of the as-synthesized CZTS electrode is studied at tri-iodide reduction reactions and is tested as Pt-free electrocatalyst in proof-of-concept type device. Under identical experimental conditions the CZTS counter electrode- and platinum electrode-based dye-sensitised solar cells result similar photocurrent density of ∼10 mA cm−2. These results encourage applications of the aero-sol controlled spray coated CZTS films as the Pt-free electrocatalyst, where reduction reaction takes a key role in energy conversion and biosensing.

U2 - 10.1016/j.matlet.2018.02.122

DO - 10.1016/j.matlet.2018.02.122

M3 - Article

SN - 0167-577X

VL - 220

SP - 122

EP - 125

JO - Materials Letters

JF - Materials Letters

ER -

Jet-nebulizer-spray coated copper zinc tin sulphide film for low cost platinum-free electrocatalyst in solar cells

Abstract

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