Reactive kinetics of carbon dioxide loaded aqueous blend of 2-amino-2-ethyl-1,3-propanediol and piperazine using a pressure drop method

Sami Ullah; Humbul Suleman; Muhammad Suleman Tahir; Muhammad Sagir; Shabbir Muhammad; Abdullah G. Al-sehemi; Masood-ur-rauf Zafar; Firas A. Abdul Kareem; Abdulhalim Shah Maulud; Mohamad Azmi Bustam

doi:10.1002/kin.2019.51.issue-4

Reactive kinetics of carbon dioxide loaded aqueous blend of 2-amino-2-ethyl-1,3-propanediol and piperazine using a pressure drop method

Sami Ullah, Humbul Suleman, Muhammad Suleman Tahir, Muhammad Sagir, Shabbir Muhammad, Abdullah G. Al-sehemi, Masood-ur-rauf Zafar, Firas A. Abdul Kareem, Abdulhalim Shah Maulud, Mohamad Azmi Bustam

Research output: Contribution to journal › Article › peer-review

Abstract

In this study, a new pressure drop method has been used to investigate the kinetics of carbon dioxide reaction with aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol (AEPD) with piperazine (PZ). The blending of a small amount of PZ with AEPD has a significant effect on the observed rate constant, kobs. It was observed that kobs values of the blend increased more than twice than the summation of kobs values of individual alkanolamines. The reaction kinetics in this study were modeled by assuming a termolecular mechanism. The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture.

Original language	English
Pages (from-to)	291-298
Number of pages	8
Journal	International Journal of Chemical Kinetics
Volume	51
Issue number	4
DOIs	https://doi.org/10.1002/kin.2019.51.issue-4
Publication status	Published - 30 Jan 2019

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10.1002/kin.2019.51.issue-4

http://doi.wiley.com/10.1002/kin.21252

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Ullah, S., Suleman, H., Tahir, M. S., Sagir, M., Muhammad, S., Al-sehemi, A. G., Zafar, M., Kareem, F. A. A., Maulud, A. S., & Bustam, M. A. (2019). Reactive kinetics of carbon dioxide loaded aqueous blend of 2-amino-2-ethyl-1,3-propanediol and piperazine using a pressure drop method. International Journal of Chemical Kinetics, 51(4), 291-298. https://doi.org/10.1002/kin.2019.51.issue-4

@article{02aea6d8579545ea83cff3ff952df596,

title = "Reactive kinetics of carbon dioxide loaded aqueous blend of 2-amino-2-ethyl-1,3-propanediol and piperazine using a pressure drop method",

abstract = "In this study, a new pressure drop method has been used to investigate the kinetics of carbon dioxide reaction with aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol (AEPD) with piperazine (PZ). The blending of a small amount of PZ with AEPD has a significant effect on the observed rate constant, kobs. It was observed that kobs values of the blend increased more than twice than the summation of kobs values of individual alkanolamines. The reaction kinetics in this study were modeled by assuming a termolecular mechanism. The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture.",

author = "Sami Ullah and Humbul Suleman and Tahir, {Muhammad Suleman} and Muhammad Sagir and Shabbir Muhammad and Al-sehemi, {Abdullah G.} and Masood-ur-rauf Zafar and Kareem, {Firas A. Abdul} and Maulud, {Abdulhalim Shah} and Bustam, {Mohamad Azmi}",

year = "2019",

month = jan,

day = "30",

doi = "10.1002/kin.2019.51.issue-4",

language = "English",

volume = "51",

pages = "291--298",

journal = "International Journal of Chemical Kinetics",

issn = "0538-8066",

publisher = "John Wiley and Sons Inc.",

number = "4",

}

Ullah, S, Suleman, H, Tahir, MS, Sagir, M, Muhammad, S, Al-sehemi, AG, Zafar, M, Kareem, FAA, Maulud, AS & Bustam, MA 2019, 'Reactive kinetics of carbon dioxide loaded aqueous blend of 2-amino-2-ethyl-1,3-propanediol and piperazine using a pressure drop method', International Journal of Chemical Kinetics, vol. 51, no. 4, pp. 291-298. https://doi.org/10.1002/kin.2019.51.issue-4

TY - JOUR

T1 - Reactive kinetics of carbon dioxide loaded aqueous blend of 2-amino-2-ethyl-1,3-propanediol and piperazine using a pressure drop method

AU - Ullah, Sami

AU - Suleman, Humbul

AU - Tahir, Muhammad Suleman

AU - Sagir, Muhammad

AU - Muhammad, Shabbir

AU - Al-sehemi, Abdullah G.

AU - Zafar, Masood-ur-rauf

AU - Kareem, Firas A. Abdul

AU - Maulud, Abdulhalim Shah

AU - Bustam, Mohamad Azmi

PY - 2019/1/30

Y1 - 2019/1/30

N2 - In this study, a new pressure drop method has been used to investigate the kinetics of carbon dioxide reaction with aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol (AEPD) with piperazine (PZ). The blending of a small amount of PZ with AEPD has a significant effect on the observed rate constant, kobs. It was observed that kobs values of the blend increased more than twice than the summation of kobs values of individual alkanolamines. The reaction kinetics in this study were modeled by assuming a termolecular mechanism. The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture.

AB - In this study, a new pressure drop method has been used to investigate the kinetics of carbon dioxide reaction with aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol (AEPD) with piperazine (PZ). The blending of a small amount of PZ with AEPD has a significant effect on the observed rate constant, kobs. It was observed that kobs values of the blend increased more than twice than the summation of kobs values of individual alkanolamines. The reaction kinetics in this study were modeled by assuming a termolecular mechanism. The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture.

U2 - 10.1002/kin.2019.51.issue-4

DO - 10.1002/kin.2019.51.issue-4

M3 - Article

SN - 0538-8066

VL - 51

SP - 291

EP - 298

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

IS - 4

ER -

Reactive kinetics of carbon dioxide loaded aqueous blend of 2-amino-2-ethyl-1,3-propanediol and piperazine using a pressure drop method

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