Study on photoelectrochemical solar cells of nanocrystalline Cd0. 7Zn0. 3Se-water soluble conjugated polymer

S.D. Chavhan, R.S. Mane, Wonjoo Lee, S. Senthilarasu, Sung-Hwan Han, J. Lee, Soo-Hyoung Lee

Research output: Contribution to journalArticlepeer-review

Abstract

Cadmium zinc selenide (Cd0.7Zn0.3Se) nanocrystalline thin films were chemically synthesized onto indium tin oxide (ITO)-coated glass substrate at relatively low temperature (<90 °C). The as-deposited films were annealed in air at 200, 300, and 400 °C for 60 min. The structure and surface morphology of the films were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The water-soluble conjugated polymer, poly(2-ethynyl-N-carboxy-propyl-pyridinium bromide) (LM3), with quaternary pyridinium salts was layered by dipping the as-deposited and annealed Cd0.7Zn0.3Se films in the aqueous polymer solution. This hybrid photoanode system was subjected to photoelectrochemical (PEC) study under a light illumination intensity of 80 mW/cm2.
Original languageEnglish
Pages (from-to)3169-3175
Number of pages7
JournalElectrochimica Acta
Volume54
Issue number11
DOIs
Publication statusPublished - 15 Apr 2009
Externally publishedYes

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