Synthesis and characterization of SBA-15 with titania clusters entrapped in micropores

Wei Wang; Mo Song

doi:10.1016/j.jnoncrysol.2006.03.067

Synthesis and characterization of SBA-15 with titania clusters entrapped in micropores

Wei Wang, Mo Song

Teesside University

Research output: Contribution to journal › Article › peer-review

Abstract

Titania-containing SBA-15s were synthesized by impregnation of titanium isopropoxide in iso-propanol. X-ray diffraction, transmission electron microscopy, and N2 sorption measurements showed that the mesostructures are intact after impregnations. Raman and UV-vis DRS spectra proved the existence of small anatase TiO2 clusters (∼1.3 nm) after three loading cycles. Disappeared micropores and unchanged mesopore volumes after three loading cycles demonstrated that majority of micropores were consumed to immobilize these small titania clusters, which could provide a new way for the development mesoporous silica-supported titania.

Original language	English
Pages (from-to)	3153-3157
Journal	Journal of Non-Crystalline Solids
Volume	352
Issue number	28-29
DOIs	https://doi.org/10.1016/j.jnoncrysol.2006.03.067
Publication status	Published - 15 Aug 2006

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10.1016/j.jnoncrysol.2006.03.067

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title = "Synthesis and characterization of SBA-15 with titania clusters entrapped in micropores",

abstract = "Titania-containing SBA-15s were synthesized by impregnation of titanium isopropoxide in iso-propanol. X-ray diffraction, transmission electron microscopy, and N2 sorption measurements showed that the mesostructures are intact after impregnations. Raman and UV-vis DRS spectra proved the existence of small anatase TiO2 clusters (∼1.3 nm) after three loading cycles. Disappeared micropores and unchanged mesopore volumes after three loading cycles demonstrated that majority of micropores were consumed to immobilize these small titania clusters, which could provide a new way for the development mesoporous silica-supported titania.",

author = "Wei Wang and Mo Song",

year = "2006",

month = aug,

day = "15",

doi = "10.1016/j.jnoncrysol.2006.03.067",

language = "English",

volume = "352",

pages = "3153--3157",

journal = "Journal of Non-Crystalline Solids",

issn = "0022-3093",

publisher = "Elsevier B.V.",

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T1 - Synthesis and characterization of SBA-15 with titania clusters entrapped in micropores

AU - Wang, Wei

AU - Song, Mo

PY - 2006/8/15

Y1 - 2006/8/15

N2 - Titania-containing SBA-15s were synthesized by impregnation of titanium isopropoxide in iso-propanol. X-ray diffraction, transmission electron microscopy, and N2 sorption measurements showed that the mesostructures are intact after impregnations. Raman and UV-vis DRS spectra proved the existence of small anatase TiO2 clusters (∼1.3 nm) after three loading cycles. Disappeared micropores and unchanged mesopore volumes after three loading cycles demonstrated that majority of micropores were consumed to immobilize these small titania clusters, which could provide a new way for the development mesoporous silica-supported titania.

AB - Titania-containing SBA-15s were synthesized by impregnation of titanium isopropoxide in iso-propanol. X-ray diffraction, transmission electron microscopy, and N2 sorption measurements showed that the mesostructures are intact after impregnations. Raman and UV-vis DRS spectra proved the existence of small anatase TiO2 clusters (∼1.3 nm) after three loading cycles. Disappeared micropores and unchanged mesopore volumes after three loading cycles demonstrated that majority of micropores were consumed to immobilize these small titania clusters, which could provide a new way for the development mesoporous silica-supported titania.

U2 - 10.1016/j.jnoncrysol.2006.03.067

DO - 10.1016/j.jnoncrysol.2006.03.067

M3 - Article

SN - 0022-3093

VL - 352

SP - 3153

EP - 3157

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 28-29

ER -

Synthesis and characterization of SBA-15 with titania clusters entrapped in micropores

Abstract

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