The effect of the variation of cation in the matrix-assisted laser desorption/ionisation-collision induced dissociation (MALDI-CID) spectra of oligomeric systems

James Scrivens; A. T. Jackson; H. T. Yates; M. R. Green; G. Critchley; J. Brown; R. H. Bateman; M. T. Bowers; J. Gidden

The effect of the variation of cation in the matrix-assisted laser desorption/ionisation-collision induced dissociation (MALDI-CID) spectra of oligomeric systems

James Scrivens, A. T. Jackson, H. T. Yates, M. R. Green, G. Critchley, J. Brown, R. H. Bateman, M. T. Bowers, J. Gidden

Research output: Contribution to journal › Article › peer-review

Abstract

The effect of the variation of the cation, on the matrix-assisted laser desorption/ionisation collision induced dissociation (MALDI-CID) spectra obtained, has been studied in a hybrid sector-orthogonal acceleration-time of flight tandem mass spectrometer for some synthetic oligomeric systems. Oligomers of poly(methyl methacrylate) and poly(styrene) in the molecular weight range of approximately 1000-3000 u were analysed. They were ionised by attachment of various alkali metal and copper and silver ions, respectively. The MALDI-CID spectra are shown to vary with different cations more from precursor ions of lower than those of higher mass-to-charge ratio.

Original language	English
Pages (from-to)	363-375
Number of pages	13
Journal	International Journal of Mass Spectrometry and Ion Processes
Volume	165-166
Publication status	Published - 1 Dec 1997

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Scrivens, J., Jackson, A. T., Yates, H. T., Green, M. R., Critchley, G., Brown, J., Bateman, R. H., Bowers, M. T., & Gidden, J. (1997). The effect of the variation of cation in the matrix-assisted laser desorption/ionisation-collision induced dissociation (MALDI-CID) spectra of oligomeric systems. International Journal of Mass Spectrometry and Ion Processes, 165-166, 363-375.

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title = "The effect of the variation of cation in the matrix-assisted laser desorption/ionisation-collision induced dissociation (MALDI-CID) spectra of oligomeric systems",

abstract = "The effect of the variation of the cation, on the matrix-assisted laser desorption/ionisation collision induced dissociation (MALDI-CID) spectra obtained, has been studied in a hybrid sector-orthogonal acceleration-time of flight tandem mass spectrometer for some synthetic oligomeric systems. Oligomers of poly(methyl methacrylate) and poly(styrene) in the molecular weight range of approximately 1000-3000 u were analysed. They were ionised by attachment of various alkali metal and copper and silver ions, respectively. The MALDI-CID spectra are shown to vary with different cations more from precursor ions of lower than those of higher mass-to-charge ratio.",

author = "James Scrivens and Jackson, {A. T.} and Yates, {H. T.} and Green, {M. R.} and G. Critchley and J. Brown and Bateman, {R. H.} and Bowers, {M. T.} and J. Gidden",

year = "1997",

month = dec,

day = "1",

language = "English",

volume = "165-166",

pages = "363--375",

journal = "International Journal of Mass Spectrometry and Ion Processes",

issn = "0168-1176",

publisher = "Elsevier B.V.",

}

The effect of the variation of cation in the matrix-assisted laser desorption/ionisation-collision induced dissociation (MALDI-CID) spectra of oligomeric systems. / Scrivens, James; Jackson, A. T.; Yates, H. T. et al.
In: International Journal of Mass Spectrometry and Ion Processes, Vol. 165-166, 01.12.1997, p. 363-375.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The effect of the variation of cation in the matrix-assisted laser desorption/ionisation-collision induced dissociation (MALDI-CID) spectra of oligomeric systems

AU - Scrivens, James

AU - Jackson, A. T.

AU - Yates, H. T.

AU - Green, M. R.

AU - Critchley, G.

AU - Brown, J.

AU - Bateman, R. H.

AU - Bowers, M. T.

AU - Gidden, J.

PY - 1997/12/1

Y1 - 1997/12/1

N2 - The effect of the variation of the cation, on the matrix-assisted laser desorption/ionisation collision induced dissociation (MALDI-CID) spectra obtained, has been studied in a hybrid sector-orthogonal acceleration-time of flight tandem mass spectrometer for some synthetic oligomeric systems. Oligomers of poly(methyl methacrylate) and poly(styrene) in the molecular weight range of approximately 1000-3000 u were analysed. They were ionised by attachment of various alkali metal and copper and silver ions, respectively. The MALDI-CID spectra are shown to vary with different cations more from precursor ions of lower than those of higher mass-to-charge ratio.

AB - The effect of the variation of the cation, on the matrix-assisted laser desorption/ionisation collision induced dissociation (MALDI-CID) spectra obtained, has been studied in a hybrid sector-orthogonal acceleration-time of flight tandem mass spectrometer for some synthetic oligomeric systems. Oligomers of poly(methyl methacrylate) and poly(styrene) in the molecular weight range of approximately 1000-3000 u were analysed. They were ionised by attachment of various alkali metal and copper and silver ions, respectively. The MALDI-CID spectra are shown to vary with different cations more from precursor ions of lower than those of higher mass-to-charge ratio.

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M3 - Article

AN - SCOPUS:0000427814

SN - 0168-1176

VL - 165-166

SP - 363

EP - 375

JO - International Journal of Mass Spectrometry and Ion Processes

JF - International Journal of Mass Spectrometry and Ion Processes

ER -

The effect of the variation of cation in the matrix-assisted laser desorption/ionisation-collision induced dissociation (MALDI-CID) spectra of oligomeric systems

Abstract

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