TY - JOUR
T1 - The pentacyanonitrosylferrate ion. Part 2. Reactions with various carbanions
AU - Butler, Anthony R.
AU - Glidewell, Christopher
AU - Chaipanich, Vinun
AU - McGinnis, Joseph
PY - 1986/1/1
Y1 - 1986/1/1
N2 - The carbanions of malononitrile, ethylmalononitrile, and dimethyl malonate react with pentacyanonitrosylferrate (nitroprusside) to form highly coloured adducts. A kinetic study has shown that, in the second and third cases, there is rate-determining reaction between carbanion and nitroprusside but, in the first, the product is that formed by a second ionisation to give [Fe(CN)5N(O)C(CN)2]4-.
AB - The carbanions of malononitrile, ethylmalononitrile, and dimethyl malonate react with pentacyanonitrosylferrate (nitroprusside) to form highly coloured adducts. A kinetic study has shown that, in the second and third cases, there is rate-determining reaction between carbanion and nitroprusside but, in the first, the product is that formed by a second ionisation to give [Fe(CN)5N(O)C(CN)2]4-.
UR - http://www.scopus.com/inward/record.url?scp=3543008407&partnerID=8YFLogxK
U2 - 10.1039/P29860000007
DO - 10.1039/P29860000007
M3 - Article
AN - SCOPUS:3543008407
SN - 1472-779X
SP - 7
EP - 9
JO - Journal of the Chemical Society, Perkin Transactions 2
JF - Journal of the Chemical Society, Perkin Transactions 2
IS - 1
ER -