The pentacyanonitrosylferrate ion. Part 2. Reactions with various carbanions

Anthony R. Butler; Christopher Glidewell; Vinun Chaipanich; Joseph McGinnis

doi:10.1039/P29860000007

The pentacyanonitrosylferrate ion. Part 2. Reactions with various carbanions

Anthony R. Butler
, Christopher Glidewell
, Vinun Chaipanich
, Joseph McGinnis

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The carbanions of malononitrile, ethylmalononitrile, and dimethyl malonate react with pentacyanonitrosylferrate (nitroprusside) to form highly coloured adducts. A kinetic study has shown that, in the second and third cases, there is rate-determining reaction between carbanion and nitroprusside but, in the first, the product is that formed by a second ionisation to give [Fe(CN)₅N(O)C(CN)₂]^4-.

Original language	English
Pages (from-to)	7-9
Number of pages	3
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	1
DOIs	https://doi.org/10.1039/P29860000007
Publication status	Published - 1 Jan 1986

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abstract = "The carbanions of malononitrile, ethylmalononitrile, and dimethyl malonate react with pentacyanonitrosylferrate (nitroprusside) to form highly coloured adducts. A kinetic study has shown that, in the second and third cases, there is rate-determining reaction between carbanion and nitroprusside but, in the first, the product is that formed by a second ionisation to give [Fe(CN)5N(O)C(CN)2]4-.",

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Y1 - 1986/1/1

N2 - The carbanions of malononitrile, ethylmalononitrile, and dimethyl malonate react with pentacyanonitrosylferrate (nitroprusside) to form highly coloured adducts. A kinetic study has shown that, in the second and third cases, there is rate-determining reaction between carbanion and nitroprusside but, in the first, the product is that formed by a second ionisation to give [Fe(CN)5N(O)C(CN)2]4-.

AB - The carbanions of malononitrile, ethylmalononitrile, and dimethyl malonate react with pentacyanonitrosylferrate (nitroprusside) to form highly coloured adducts. A kinetic study has shown that, in the second and third cases, there is rate-determining reaction between carbanion and nitroprusside but, in the first, the product is that formed by a second ionisation to give [Fe(CN)5N(O)C(CN)2]4-.

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The pentacyanonitrosylferrate ion. Part 2. Reactions with various carbanions

Abstract

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